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Dissolution Kinetics of Hydrogenated Iron in Acidic Chloride Electrolyte |
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18.09.2008 г. |
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Dissolution Kinetics of Hydrogenated Iron in Acidic Chloride Electrolyte A. I. Marshakov and T. A. Nenasheva Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences,
Leninskii pr. 31, Moscow, 119991 Russia e-mail:
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Received December 23, 2004 Abstract — The rate constants of the discharge of H+ ions and the molization of adsorbed H atoms and the constant of hydrogen exchange between the surface and bulk of iron in acidic chloride electrolytes were determined. The effect of sorbed hydrogen on the kinetics of iron dissolution was studied with the use of a bipolar membrane electrode.
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