Kinetics of Galvanostatic Chloride Pitting of Stainless Steels in Chloride Solutions
30.09.2008 г.

Kinetics of Galvanostatic Chloride Pitting of Stainless Steels in Chloride Solutions

I. I. Zamaletdinov

 

Perm State Technical University, Komsomol’skii pr. 29a, Perm, 614600 Russia

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Received March 12, 2001; in final form, July 15, 2003

 

Abstract — To check the theory, the corrosion of steels 12frame018frame110frame2 and 10frame317frame413frame52frame6 is studied during galvanostatic polarization at different frame7, current densities, and temperatures. The morphology and size distribution of pits are discussed. In E vs. log curves are shown to demonstrate a single linear segment for steel 12frame818frame910frame10 and two linear segments for 10frame1117frame1213frame132frame14 (as for pure Fe, according to the literature data [12]), namely, the initial segment with a steep slope and the later one with more gentle slope. The single slope E/frame15of steel 12frame1618frame1710frame18 and the later (gentle) slope, which is observed for both steel 10frame1917frame2013frame212frame22 and Fe, correspond to those predicted in [3, 4, 7], while the earlier steep slope corresponds to crevice-type pitting.