Kinetics of Galvanostatic Chloride Pitting of Stainless Steels in Chloride Solutions |
30.09.2008 г. |
Kinetics of Galvanostatic Chloride Pitting of Stainless Steels in Chloride Solutions I. I. Zamaletdinov Perm State Technical University, Komsomol’skii pr. 29a, Perm, 614600 Russia e-mail:
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Received March 12, 2001; in final form, July 15, 2003 Abstract — To check the theory, the corrosion of steels 121810 and 1017132 is studied during galvanostatic polarization at different , current densities, and temperatures. The morphology and size distribution of pits are discussed. In E vs. log curves are shown to demonstrate a single linear segment for steel 121810 and two linear segments for 1017132 (as for pure Fe, according to the literature data [12]), namely, the initial segment with a steep slope and the later one with more gentle slope. The single slope E/of steel 121810 and the later (gentle) slope, which is observed for both steel 1017132 and Fe, correspond to those predicted in [3, 4, 7], while the earlier steep slope corresponds to crevice-type pitting.
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