Supramolecular Bisporphyrin Cages: Design and Ways of Self-Assembly of Supramolecular Bisporphyrin Structures for Molecular Nanomotors and Nanosensors

Yu. P. Yashchuk, V. S. Tyurin, and I. P. Beletskaya

Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences,
Leninskii pr. 31, Moscow, 119991 Russia

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Received March 6, 2008

Abstract — Self-assembly of supramolecular ensembles of coordination bisporphyrins was studied in reactions of meso-tetrakis(3-hydroxyphenyl)porphyrinatozinc with LaCl₃, MnCl₂, CrCl₃, and SnCl₂ and exodentate ligands (1,4-diazabicyclo[2.2.2]octane and 4,4'-bipyridyl). A design and ways of self-assembly of bisporphyrins structures were developed.