|
Recent Trends in Experimental and Theoretical Investigations of Chemisorptions on Metal-Electrolyte |
|
11.02.2009 г. |
|
Recent Trends in Experimental and Theoretical Investigations of Chemisorptions on Metal-Electrolyte Interface. In Situ Spectroscopic Studies and the Density Functional Theory Calculations V. A. Marichev* Department of Chemistry, University of Western Ontario, London, N6A 5B7, Ontario, Canada *e-mail:
Этот e-mail защищен от спам-ботов. Для его просмотра в вашем браузере должна быть включена поддержка Java-script
Received May 14, 2007 Abstract — New trends in experimental and theoretical investigations of chemisorption on electrodes are considered on examples of in situ spectroscopic studies and the density functional theory calculations. The partial charge transfer during ionic and molecular adsorption from aqueous solutions on coinage and platinum metals and the thermodynamic uncertainty regarding the direction of the charge transfer are discussed. PACS numbers: 68.43.-h, 78.30.-j DOI: 10.1134/S2070205109010018
|