Fluctuation Formation Model and Operation Mechanism of an Inhibiting Layer on Metals. I. Origination of an Inhibitor Boundary Layer

Yu. A. Popov and N. A. Koval’chukov

Karpov Institute of Physical Chemistry, ul. Vorontsovo pole 10, Moscow, 105064 Russia
Russian Peoples Friendship University, ul. Mikluho-Maklaya 6, Moscow, 117198 Russia
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Received January 21, 2009

Abstract — A mechanism of the origination of electrolyte solution fluctuations on S surface of the anodically dissolved metal is discussed. Heterogeneous formation kinetics of a two-component inhibitor nucleus in a strong field of  the electric double layer within fluctuation is considered.