Study of the Sorption-Kinetic Properties of Carbon Molecular Sieves

A. V. Berveno^a,b and V. P. Berveno^b

^a Kemerovo State University, ul. Krasnaya 6, Kemerovo, 650043 Russia

^b Institute of Solid-State Chemistry and Mechanochemistry (Kemerovo Branch), Siberian Division,
Russian Academy of Sciences, Kemerovo, Russia

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Received December 10, 2008

Abstract — To elucidate the role of the electron-exchange properties of arene molecules that form the pore walls of carbon molecular sieves in their interactions with sorbate molecules, the correlation between the electron-exchange and sorption-kinetic properties was studied. The electron-exchange properties were estimated by using quantum-chemical modeling based on the energies of formation of singly charged anions and cations and neutral (both oxidized and reduced) molecules.

PACS: 68.43.-h