Synthesis of meso-Substituted Porphyrins as Precursors in Creating Highly Ordered Electroluminescent Polymer Materials

E. V. Vinogradova, Yu. Yu. Enakieva, Yu. G. Gorbunova*, and A. Yu. Tsivadze

Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskii pr. 31, Moscow, 119991 Russia

*e-mail: Этот e-mail защищен от спам-ботов. Для его просмотра в вашем браузере должна быть включена поддержка Java-script

Received March 13, 2009

Abstract — Methods of obtaining porphyrin-containing polymer materials that have electroluminescent properties are analyzed. Based on the data, a strategy for producing the most effective porphyrin precursors for the further synthesis of highly ordered polymer materials is developed. Synthetic approaches are found and twomeso-substituted porphyrins, i.e., 5,15-diphenyl-10,20-dibromoporphyrin (1a) and 5,15-diethynylphenylpor-phyrin (2a), are synthesized.

PACS numbers: 78.60.Fz